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I'm no expert, but I think thats a good thing

Late August to September is generally the most ideal time for dividing these plants.

I guess it comes down to which one you like the looks of better in that garden location. If the peonies are giving you a lot of joy, then I would move the rose bushes to another but still sunny location. The rose bushes must be floribunda roses as those tend to stay shorter. Hybrid teas or Grandifloras should have given the peonies a run for their money in the height department. I would not move the rose bushes if they are very actively growing at this time, however, as it could kill them.Transplant in early spring once the ground is workable.

First of all, do not store any seed in the freezer, as this will normally kill them. The refigerator or an airtight container in a dark location would be better. That being said, peonies are usually propagated by grafting or root division. Many peonies are infertile and do not produce seeds. However, for those that do, collect the seeds as soon as the pods begin to open. Place them in a sealed plastic bag with barely moist vermiculite or soilless germination mix. Place the sealed bags in a warm area and ensure they remain moist (but not wet). Leave them in the warmth until the roots appear, which can take anywhere from a few weeks to several months.

Once the roots appear and are about an inch long, move the bag to a cool location, such as a refrigerator, for about 10-12 weeks, after which you can pot them up in a soilless germination mix. Note: seeds can also be sown directly in the ground provided the conditions for dormancy and growth are present. However, it will usually take until the second spring before shoots appear.

Any high phosphorus fertilizer, like bone meal, it good for any plant that blooms. Plants can't bloom without it.

Early fall is a good time to dig up or transplant peonies.